邻苯二酚在活化玻碳电极上的电化学行为

邻苯二酚( QH2,儿茶酚)等有机化合物是人体内的电活性物质,直接参与人体内的各种生理过程.     

水杨酸在多壁碳纳米管修饰电极上的电化学行为及其测定

用循环伏安法(CV)研究了水杨酸(SA)在多壁碳纳米管修饰玻碳电极上的电化学行为,并初步探讨了反应机理.实验结果表明,水杨酸在该电极上为一个2e/H~+的完全不可逆过程.在pH=5.0的磷酸盐缓冲溶液(PBS)中,用循环伏安法在该电极上测定了水杨酸.方法线性范围为2.0×10~(-5)～1.0×10~(-3)mol/L,检出限为8.93×10~(-6)mol/L.将该电极用于药品分析,结果令人满意.     

A Model with Exact Inflationary Solution in Finsler Universe

In this paper, using the Gravity’s Rainbow theory, we introduce rainbow metric into rainbow Robertson-Walker metric, and obtain a model which depends on the energy of probe particles. Furthermore, we research on an exact inflationary solution of the model, and it can be consistent with the conclusions of observation. The results of our research show that some details in inflation depend on the energy of particles which are observed by observers.     

A newton approach for long term stability studies in power systems

This paper deals with the problem of transient and long term stability of power systems. The issue of assessing both horizons of analysis is particularly focused. This is because the long term stability may be studied by a simplified algebraic model which also captures some dynamic characteristics. Such an approach is called quasi-dynamic model. The idea of analyzing the transient period and migrating to the quasi-dynamic model is addressed in this paper. The theoretical foundation is presented and some tests are carried out in order to validate the approach.     

Joint transmitter adaptation and power control for cognitive radio networks with target SIR requirements

In this paper we study joint transmitter adaptation and power control in the uplink of Cognitive Radio (CR) networks with target values imposed on the signal-to-interference +noise-ratios (SINR) at the CR receiver. We use a framework based on block transmissions and linear precoders to formulate this as a constrained optimization problem for which we discuss the conditions that must be satisfied by the optimal solution. We also present an algorithm which adapts the transmit precoder and power values incrementally until a fixed point is reached where the specified target SINRs are achieved with minimum transmitted power. Convergence of the proposed algorithm is discussed and is illustrated with numerical examples obtained from simulations.     

Global existence of weak solutions for the 3D chemotaxis-Navier–Stokes equations

In this paper, we consider the Cauchy problem for the three dimensional chemotaxis-Navier–Stokes equations. By exploring the new a priori estimates, we prove the global existence of weak solutions for the 3D chemotaxis-Navier–Stokes equations.     

Merit functions and error bounds for constrained mixed set-valued variational inequalities via generalized f-projection operators

In this paper, we introduce and investigate a constrained mixed set-valued variational inequality (MSVI) in Hilbert spaces. We prove the solution set of the constrained MSVI is a singleton under strict monotonicity. We also propose four merit functions for the constrained MSVI, that is, the natural residual, gap function, regularized gap function and D-gap function. We further use these functions to obtain error bounds, i.e. upper estimates for the distance to solutions of the constrained MSVI under strong monotonicity and Lipschitz continuity. The approach exploited in this paper is based on the generalized f-projection operator due to Wu and Huang, but not the well-known proximal mapping.     

Interaction between lactose and cadmium chloride in aqueous solutions as seen by diffusion coefficients measurements

Diffusion coefficients of an aqueous system containing cadmium chloride 0.100 mol · dm⁻³ and lactose at different concentrations at 25 °C have been measured, using a conductimetric cell and an automatic apparatus to follow diffusion. The cell relies on an open-ended capillary method and a conductimetric technique is used to follow the diffusion process by measuring the resistance of a solution inside the capillaries, at recorded times. From these results and by ab initio calculations, it was possible to obtain a better understanding of the effect of lactose on transport of cadmium chloride in aqueous solutions.     

Controlled formation of novel supramolecular microbelts or microprisms from aniline and H2PdCl4 driven by coordination and π–π interactions

In this communication, I report the formation of novel supramolecular one-dimensional (1D) structures including microbelts and microprisms by a direct mix of aniline and H₂PdCl₄ aqueous solutions at room temperature. As-formed supramolecular structures were characterised by scanning electron microscopy, X-ray photoelectron spectra and X-ray diffraction techniques. Both coordination and π–π interactions are expected to be responsible for these 1D microstructures. It suggests that the molar ratio of the reactants is crucial to the formation of such 1D structures.     

三价磷介入的Kukhtin-Ramirez反应研究进展

Kukhtin-Ramirez反应是有机化学中一类重要的极性反转反应.利用三价磷的还原性对α-羰基酮化合物进行极性反转,所生成的Kukhtin-Ramirez活性中间体在诸多转化中都展现出了其作为1,1-偶极子的化学性质.近年来关于该活性中间体的反应研究主要包括:极性X—H键插入反应、还原性加成反应、形式[2+1]环加成反应、形式[4+1]环加成反应、形式[4+2]环加成反应.这些转化为一些重要的多官能团化合成中间体及结构复杂的环状化合物提供了高效简洁的合成方法,凸显了Kukhtin-Ramirez极性反转反应在有机合成中的重要性.